Phase Equilibrium Studies Bearing on the Limestone-Assimilation Hypothesis

Author(s):  
DAVID H. WATKINSON ◽  
PETER J. WYLLIE
2020 ◽  
Vol 6 (1) ◽  
pp. 9
Author(s):  
Małgorzata E. Zakrzewska ◽  
Ana B. Paninho ◽  
M. Fátima C. Guedes da Silva ◽  
Ana V. M. Nunes

Selective water (by-product) separation from reaction mixtures stands as an important process intensification strategy for equilibrium-limited reactions. In this work, the possibility of using a high-pressure biphasic reaction media composed of a hydrophobic ionic liquid, 1-hexy-3-methylimidazolium tetracyanoborate, and carbon dioxide was explored for levulinic acid production from 1,4-butanediol. Vapour-liquid equilibrium measurements were performed for the binary (diol+CO2), ternary (diol+CO2+IL), and quaternary systems (diol+CO2+IL+water), at 313.2 K and pressures up to 18 MPa. The static analytical method was used in a high-pressure phase equilibrium apparatus equipped with a visual sapphire cell. The capability of the quaternary system to perform physical water separation is discussed in this paper.


1969 ◽  
Vol 116 (11) ◽  
pp. 1612 ◽  
Author(s):  
Carl E. Johnson ◽  
Melvin S. Foster

1993 ◽  
Vol 191 (1) ◽  
pp. 9-13 ◽  
Author(s):  
R. Sridharan ◽  
T. Gnanasekaran ◽  
C.K. Mathews

1983 ◽  
pp. 89-99 ◽  
Author(s):  
T. Y. Tien ◽  
G. Petzow ◽  
L. J. Gauckler ◽  
J. Weiss

2000 ◽  
Vol 64 (13) ◽  
pp. 2339-2350 ◽  
Author(s):  
L.T Elkins ◽  
V.A Fernandes ◽  
J.W Delano ◽  
T.L Grove

2002 ◽  
Vol 33 (6) ◽  
pp. 827-838 ◽  
Author(s):  
Ghasem Roghani ◽  
Evgueni Jak ◽  
Peter Hayes

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